The crystal structure of sodium tungsten bronze (NaxWO3) is affected by the value of x. When x < 0.1, NaxWO3 has a WO3 structure, that is, a cubic crystal with WO6 octahedron as its structural unit. When 0.1 < x < 0.35, NaxWO3 is a tetragonal crystal. When 0.35 < x < 1, NaxWO3 is a perovskite structure with Na+ vacancies. The close-packed structure, chemical inertness, metallic luster, and electrical conductivity of sodium tungsten bronze make it possible to become a new type of solid electrolyte.
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