How Was Tungsten Bronze Discovered And Named?

In 1949, A. Magne li synthesized the tungstate KxWO3 (0<x<1) with the common vertex structure of WO6 octahedral units, and found that it had a bronze-like color and brightness, so the compound with a similar structure was called For tungsten bronze type material. This tungsten bronze material has unique and excellent properties in ferroelectricity, piezoelectricity, pyroelectricity, nonlinear optics, etc. Mineral materials are the second largest category of electronic materials.

Around 1993, photorefractive nonlinear optics developed rapidly as a new branch of optics, and series crystals of the tungsten bronze family (such as SBN, KNSBN) have made great progress in material preparation and device design, an important The reason is that its open structure is convenient for doping modification. Among them, strontium calcium sodium niobate crystal has many characteristics such as high electro-optic coefficient, high optical figure of merit, high Curie point, short growth cycle, etc., and is considered to be a new type of photorefractive material with potential application value.

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