Trimethylaluminum can methylate tungsten hexachloride to form hexamethyltungsten:
WCl6 +3 Al2(CH3)6 → W(CH3)6 + 3 Al2(CH3)4Cl2
Treatment with butyllithium yields reagents that can be used for the deoxygenation of epoxides.
The chlorine atom of WCl6 can be replaced by many ligands, including Br−, NCS− and RO− (R = alkyl, aryl).
Reduction of WCl6 can form tungsten pentachloride and tungsten tetrachloride.
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