How to Prepare Ammonium Metatungstate?

A pure tungsten compound preparation method for producing ammonium metatungstate by using ammonium paratungstate, ammonium tungstate and sodium tungstate solution as raw materials.

Ammonium metatungstate is an important compound in the tungsten smelting process. The chemical composition of the product is (NH4) 6H2 W12O40•nH2O or 3 (NH4)2O•12WO3•(n+1)H2O. Ammonium metatungstate has a wide range of uses, and can be used as a raw material for catalysts, capacitors, nuclear shielding, flame retardants, and corrosion inhibitors. Excellent raw material of silicotungstic acid.

There are many preparation methods of AMT, and the principle process flow of the main preparation methods is shown in the figure.

Using ammonium tungstate solution as raw material, ammonium metatungstate solution is first prepared by solvent extraction or ion exchange method (USA), and there is also solvent extraction method using sodium tungstate solution as raw material (Europe); currently, ammonium paratungstate is mainly used in China (APT) as the starting material thermal dissociation method.

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