Tungsten tetrabromide (WBr4) and tungsten dibromide (WBr2) differ somewhat in their oxidation states:
Tungsten tetrabromide (WBr4): The tungsten atoms in tetrabromotungsten exhibit a +4 oxidation state, and each tungsten atom is surrounded by four bromine atoms, forming a bond between the tungsten and the four bromine atoms.
Tungsten dibromide (WBr2): The tungsten atoms in tungsten dibromide exhibit a +2 oxidation state, and each tungsten atom is surrounded by two bromine atoms, forming a bond between tungsten and two bromine atoms.
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