Tungsten tetrabromide (WBr4) and tungsten tribromide (WBr3) are two different compounds, and there are obvious differences in their crystal structures.
Crystal structure of tungsten tetrabromide (WBr4):
The crystal structure of tungsten tetrabromide belongs to the hexagonal crystal system. Its cell structure consists of tungsten atoms and four bromine atoms. The tungsten atom is located in the center of the cell, while the four bromine atoms occupy the vertices of the cell, forming a hexagonal structure.
Crystal structure of tungsten tribromide (WBr3):
The crystal structure of tungsten tribromide belongs to the orthorhombic crystal system. Its cell structure consists of tungsten atoms and three bromine atoms. The tungsten atom is located in the center of the cell, while the three bromine atoms occupy the vertices of the cell, forming a rectangular structure.
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