メタタングステン酸アンモニウムからの三酸化タングステンの生産

メタタングステン酸アンモニウム(AMT)は、熱分解により高純度の三酸化タングステン(WO₃)を直接生産できます。プロセスは以下の通りです:

  1. AMTを酸化雰囲気下で300~500℃に加熱し、WO₃、アンモニア(NH₃)、および水蒸気(H₂O)に分解します。
  2. 生成したWO₃を回収し、必要に応じて結晶性を高めるためにさらに焼成します。
    WO₃は、電気変色材料(例:スマートウィンドウ)やガスセンサー(例:NO₂検出)の主要成分です。AMTの利点は、分解生成物の純度が高く、不純物が少ないため、エレクトロニクス業界の要求に応えます。一方、アンモニウムパラタングステン(APT)からWO₃を生産するにはより高い温度(700~800℃)が必要で、追加の工程が必要になる場合があります。

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